三门核电土石方工程中深孔爆破法的应用

浙江三门核电平基工程中采用深孔台阶爆破进行土石方开挖,对底板的平整度和完整性有很高的要求,超挖不得超过20cm,不容许欠挖。为此,根据可爆性对开挖区内的岩石进行分级,分别采用不同的钻爆参数,同时采取了预留保护层爆破、无超深爆破、底部空气间隔装药等技术措施,确保了底板的开挖质量。     

基于有限元法的石油射孔枪弹间干扰研究

石油射孔弹顺序起爆后,弹间冲击波相互作用是一个高度非线性的力学过程。基于有限元法对这一过程进行显式动力分析,由计算结果得知,高孔密射孔枪弹间干扰产生的主要原因是下位弹在不对称的压力场起爆。设计的不同孔密和不同爆速的导爆索两种情形的爆轰试验结果表明,弹间间距越小(即孔密的增加),弹间干扰越严重;随着导爆索爆速的降低,下位弹射流头部质量集中的"中间"偏转角度增大,上位弹对其干扰越明显。以上结论可用于高孔密射孔枪的优化设计。     

Effect of heat loss on the syngas production by fuel-rich combustion in a divergent two-layer burner

The effect of heat loss on the syngas production from partial combustion of fuel-rich in a divergent two-layer burner is numerically studied using two-dimensional model with detailed kinetics GRI-Mech 1.2. Both the radiation and wall heat losses to the surrounding are considered in the computations. It is shown that two types heat losses have different effects on the syngas production. The radiation heat loss has significant effect on the syngas temperature and the syngas temperature is dropped as radiation heat loss is increased, but it has neglected effect on the reforming efficiency and methane conversion efficiency. The wall heat loss has a comprehensive effect on the syngas production. The wall heat loss not only reduces the conversion efficiency, but also significantly decreases the syngas temperature. The effect of wall heat loss becomes weak as the equivalence is increased. The reforming efficiency drops from 0.440 to 0.424 for equivalence ratio of 2 and mixture velocity of 0.17 m/s for the predictions between adiabatic wall and non-adiabatic conditions.     

Cloning,sequencing and structural analysis of membrane-bound polyphenol oxidase from Granny Smith apples (Malus × domestica Borkh)

The gene sequence coding for the membrane-bound polyphenol oxidase (mPPO) with a length of 1761 bp was cloned by PCR method and shown to contain one highly conserved sequence encoding a di-copper-binding region. The predicted three-dimensional structure of mPPO indicated that the active site was located near two copper ions and composed of a typical bundle of four α-helices. Each of the two catalytic copper ions was coordinated with three histidine residues in the hydrophobic pocket, yielding His 180, His 201, His 210, His 332, His 336 and His 366. Docking studies showed that 4-methylcatechol and chlorogenic acid have different binding models due to different ligand sizes and binding sites in the active centre, and it was found that the smaller compound exhibited a higher affinity for mPPO. Molecular dynamic simulation results indicated that Phe 353 is important in controlling enzymatic activity through influencing substrate coordination in the active site.     

Direct shear behavior of gravel-rubber mixtures: Discrete element modeling and microscopic investigations

In this paper, a newly developed 3-dimentional discrete element model (DEM) for gravel-rubber mixtures (GRMs), namely DEM4GRM, that is capable of accurately describing the macro-scale shear response (from small to large deformation) of GRMs in a direct shear box apparatus is presented. Rigid gravel grains are modelled as simple multi-shape clumps, while soft rubber particles are modeled by using deformable 35-ball body-centered-cubic clusters. Mixtures are prepared with different volumetric rubber content (VRC) at 0, 10, 25, 40 and 100%, statically compressed under 30, 60 and 100 kPa vertical stress and then sheared, by closely simulating a reference laboratory test procedure. The variation of micro-scale factors such as fabric, normal and tangential force anisotropy is carefully examined throughout the shearing process and described by means of novel micro-mechanical relationships valid for GRMs. Moreover, strong-force chains are scrutinized to identify the transition from rigid to soft granular skeleton and gain insights on the load transfer and deformation mechanisms of GRMs. It is shown that the development of the fabric and force anisotropy during shearing is closely related to the macro-scale shear strength of GRMs, and strongly depends on the VRC. Besides, strong-force chains appear to be primarily formed by gravel-gravel contacts (resulting in a rigid-like mechanical behavior) up to VRC = 30%, and by rubber-rubber contacts (causing a soft-like mechanical response) beyond VRC = 60%. Alternatively, at 30% < VRC < 60%, gravel-rubber contacts are predominant in the strong-force network and an intermediate mechanical behavior is observed. This is consistent with the behavioral trends observed in the macro- and micro-mechanical responses.     

模具设计与制造专业群虚拟仿真实训基地建设路径研究

针对模具设计与制造专业群实训教学开展过程中存在的问题,开展专业群虚拟仿真实训基地的建设,通过精密模具智能制造生产线仿真实训工厂、模具数字化设计及智能成型单元综合应用平台、开放共享课程资源等3个方面内容的建设,引入行业新技术、新工艺、新标准,确保虚拟仿真教学资源与学生职业能力培养相一致。基地建设依托智能制造新技术,以培养高层次复合型技术技能人才为主线,满足实训教学为核心,多方共享为目标,助力区域经济发展,服务"鲁班工坊"国际化建设,最终实现虚拟仿真实训基地区域示范性效果。     

Influence of thermal runaway in styrene–acrylonitrile bulk copolymerization revealed by computational fluid dynamics modeling

The computational fluid dynamics (CFD) and kinetic-based moment methods coupled approach is adopted to simulate the bulk copolymerization of styrene–acrylonitrile (SAN) in a stirred tank reactor. Numerical simulations are carried out to investigate the impacts of impeller speed, monomer ratio, initiator ratio, and initial reaction temperature on the copolymerization process and product properties. Particularly, the Chaos theory is selected as a criterion for evaluating the occurrence of the thermal runaway. The Flory's and Stockmayer's distributions are employed to calculate chain length distribution and copolymer composition distribution of copolymer. The simulation results highlight that the appearance of thermal runaway can be postponed by properly increasing the rotation speed, decreasing the initiator loadings, initial acrylonitrile contents and initial reactor temperature. Furthermore, significant differences exist in the product properties that predicted by the ideal and non-ideal models, which demonstrates that the temperature heterogeneity plays a crucial role in SAN copolymerization. This study could offer references for the safe operation and design of polymerization processes.     

Lanthanide doped fluorosilicate glass-ceramics:A review on experimental and theoretical progresses

Significant developments have been made in the past few decades for lanthanide(Ln)ions doped fluorosilicate glass-ceramics(Flusi-GCs).As novel generation of luminescence materials with a wide range of applications,Flusi-GCs as a single host combine the advantages of glass and ceramics/crystals as well as fluorides and silicates.In this review,the chemical design principles and experimental procedures of Flusi-GCs are summarized in detail.Flusi-GCs are categorized as those containing PbxCd_1-xF₂,RF₃(R=Y,La,Gd),MF₂(M=Ca,Sr,Ba),xMF₂-yRF₃(R=Y,La-Lu),mAF-nRF₃(A=Li,Na,K),KTF₃(T=Zn,Mn)and K2 SiF6 nanocrystals(NCs).Theoretical breakthroughs mainly by molecular dynamic(MD)simulation have been recapitulated as efficient routes for composition-design,nano-crystallization-prediction,and performance-optimization of Flusi-GCs containing target fluoride NCs.Essential research progresses pertaining photonic applications have been made in random lasers,communication amplifiers,optical fibers,spectral converters,white light-emitting-diodes(WLEDs),and thermal sensors.In the end,we propose three future research directions for Flusi-GCs.     

A novel 4D resolution imaging method for low and medium atomic number objects at the centimeter scale by coincidence detection technique of cosmic-ray muon and its secondary particles

The muon radiography imaging technique for high-atomic-number objects(Z) and large-volume objects via muon transmission imaging and muon multiple scattering imaging remains a popular topic in the field of radiation detection imaging. However, few imaging studies have been reported on low and medium Z objects at the centimeter scale. This paper presents an imaging system that consists of three layers of a position-sensitive detector and four plastic scintillation detectors. It acquires data by co...